Dehydrogenative Cross??Coupling of Primary and Secondary Alcohols

S Musa, L Ackermann, D Gelman

文献索引：Musa, Sanaa; Ackermann, Lutz; Gelman, Dmitri Advanced Synthesis and Catalysis, 2013 , vol. 355, # 14-15 p. 3077 - 3080

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被引用次数: 23

摘要

Abstract: Homo-and cross-coupling of alcohols resulting in the formation of the corresponding ketones in very good to excellent yield was realized through the one-pot sequence of dehydrogenation/aldol condensation/hydrogenation accompanied by the release of molecular hydrogen. The dehydrogenation and hydrogenation steps are catalyzed by the previously reported ruthernium-and iridiumbased ligand-metal ...