Organometallics

Synthesis and Characterization of (β-Diketonato) silver Vinyltriethylsilane Compounds and Their Application to CVD of Silver Thin Films. Crystal Structure of the (2, 2- …

KM Chi, KH Chen, SM Peng, GH Lee

文献索引：Chi, Kai-Ming; Chen, Kuo-Hsien; Peng, Shie-Ming; Lee, Gene-Hsiang Organometallics, 1996 , vol. 15, # 10 p. 2575 - 2578

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被引用次数: 38

摘要

The reaction of Ag2O with β-diketones in the presence of vinyltriethylsilane (VTES) produced new organosilver compounds of empirical formula (β-diketonato) Ag (VTES), and single-crystal structural determination of (fod) Ag (VTES) showed that it is a dimeric species and each silver atom is 4-coordinate. Hot-wall chemical vapor deposition experiments revealed that (hfac) Ag (VTES) is suitable as a precursor to deposit silver films in the ...