Organic Letters 2002-06-27

An air-stable palladium/N-heterocyclic carbene complex and its reactivity in aryl amination.

Mihai S Viciu, Rebecca M Kissling, Edwin D Stevens, Steven P Nolan

文献索引：Org. Lett. 4 , 2229, (2002)

摘要

[reaction: see text] The synthesis and characterization of [Pd(IPr)Cl(2)](2) (1), an air- and moisture-stable complex, is reported. The utilization of 1 as a catalyst for amination of aryl chlorides and bromides with a variety of amine coupling partners under mild conditions is described. The amination reactions with 1 show a remarkable insensitivity to oxygen and water, and thus the amination reactions could be performed in air on the benchtop with undried reagent grade solvents and substrates with small effects on reaction times and conversions.

结构式	名称/CAS号	分子式	全部文献
	1,3-双(2,6-二异丙基苯基)咪唑-2-亚基 CAS:244187-81-3	C₂₇H₃₈N₂

The anti-DNA antibody: origin and impact, dogmas and controv...
2015-09-01
[Nat. Rev. Rheumatol. 11 , 530-40, (2015)]

Effects of Fetal and Neonatal Murine Peripheral Blood Mononu...
2015-10-01
[Transplant. Proc. 47 , 2523-7, (2015)]

Arduengo, A. J., III; Gamper, S. F. et al.
[J. Am. Chem. Soc. 116 , 4391, (1994)]

Zhang, C.; Huang, J. et al.
[J. Org. Chem. 64 , 3804, (1999)]

Huang, J.; Nolan, S. P.
[J. Am. Chem. Soc. 121 , 9889, (1999)]

An air-stable palladium/N-heterocyclic carbene complex and its reactivity in aryl amination.

摘要

相关化合物