(π??Allyl) Pd Complexes Containing N??Heterocyclic Carbene and Pseudohalogen Ligands–Synthesis, Reactivity toward Organic Isothiocyanates and Isocyanides, and …

HK Kim, JH Lee, YJ Kim, Z Nu Zheng…

文献索引：Kim, Hyun-Kyung; Lee, Jung-Hyun; Kim, Yong-Joo; Nu Zheng, Zhen; Lee, Soon W. European Journal of Inorganic Chemistry, 2013 , # 28 p. 4958 - 4969

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被引用次数: 2

摘要

Abstract Dinuclear (π-allyl) palladium chlorides,[(π-allyl) Pd (μ-Cl)] 2, were cleaved by N- heterocyclic carbenes (NHCs) to give mononuclear (π-allyl) palladium–NHC chlorides,[(π- allyl) Pd (Cl)(NHC)](1–6)[NHC= 1, 3-bis (2, 6-diisopropylphenyl) imidazol-2-ylidene (IPR), 1, 3-bis (2, 6-diisopropylphenyl)-4, 5-dihydroimidazol-2-ylidine (SIPR), 1, 3-bis (2, 4, 6- trimethylphenyl) imidazol-2-ylidene (IMes)]. Complexes 1–6 were subsequently treated ...