The synthesis of antigenic glycopeptides, 2-acetamido-N-(. BETA.-L-aspartyl)-2-deoxy-4-O-. BETA.-(D-galactopyranosyl)-. BETA.-D-glucopyranosylamine.(N- …
MAEM Shaban, RW Jeanloz
文献索引：Shaban, Mohammed Abd El-Monem; Jeanloz, Roger W. Bulletin of the Chemical Society of Japan, 1981 , vol. 54, # 11 p. 3570 - 3576
The title compound, serving as intermediate in the chemical and biochemical synthesis of glycopeptides and as a reference substance in the structure elucidation of glycoproteins, was synthesized. 2-Acetamido-4-O-allyl-3, 6-di-O-benzyl-2-deoxy-β-D-glucopyranosyl azide was reduced to the corresponding β-D-glucosylamine and coupled with 1-benzyl N- benzyloxycarbonyl-L-aspartate to give 2-acetamido-4-O-allyl-3, 6-di-O-benzyl-N-[(S)-3- ...
