The Journal of Organic Chemistry

Preparation of. alpha.-halo sulfoximines

CR Johnson, HG Corkins

文献索引：Johnson,C.R.; Corkins,H.G. Journal of Organic Chemistry, 1978 , vol. 43, p. 4136 - 4140

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被引用次数: 15

摘要

(?-Halo sulfoximines have been prepared by the chlorination of N-methyl-and N- chlorosulfoximines with tert: butyl hypochlorite (BHC) and by amination of cu-halo sulfoxides with mesitylsulfonyloxyamine. cu-Chlorination of S-tiutyl-lL, S-dimethylsulfoximine with BHC occurred only at the S-methyl. Reaction of S-butyl-or S-ethyl-N-methvl-S-phenylsulfoximine with RHC gave a single diastereomer.