Journal of Fluorine Chemistry

Methode quantitative pour la preparation de perfluoroalcoyl-ethanol RF CH 2 CH 2 OH a partir de perfluoroalcoyl-2 iodo-1 ethane RF CH 2 CH 2 I.(RF C n F 2n+ 1, n …

H Blancou, S Benefice, A Commeyras

文献索引：Blancou,H.; Benefice,S. Journal of Fluorine Chemistry, 1983 , vol. 23, p. 57

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被引用次数: 8

摘要

Abstract A new quantitative method to prepare the perfluoroalkyl ethanol (RF CH 2 CH 2 OH) via an organometallic route is described. The iodoperfluoroalkyl ethane (RF CH 2 CH 2 I) reacts with the metallic zinc-copper couple in particular solvents, especially butyl phosphate. The oxidation of the organozinc compound RF CH 2 CH 2 ZnI leads to an alcohol.