Tetrahedron

Hypervalent iodine-mediated oxygenative phenol dearomatization reactions

…, T Garnier, LB Rojas, J Charris, D Deffieux, S Quideau

文献索引：Pouysegu, Laurent; Sylla, Tahiri; Garnier, Tony; Rojas, Luis B.; Charris, Jaime; Deffieux, Denis; Quideau, Stephane Tetrahedron, 2010 , vol. 66, # 31 p. 5908 - 5917

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被引用次数: 63

摘要

Both λ3-and λ5-iodanes have proven to be useful reagents in the oxygenative dearomatization of phenols, and exploitations of their chemistry in the conception of both substrate-and reagent-controlled asymmetric variants of such a transformation of great value for natural product synthesis have shown evident signs of success. Moreover, the use of stabilized IBX (ie, SIBX) in our methodology for O-demethylation of 2-methoxyphenols, ...