Iron (III)??Catalyzed Halogenations by Substitution of Sulfonate Esters

N Ortega, A Feher??Voelger, M Brovetto…

文献索引：Ortega, Nuria; Feher-Voelger, Andres; Brovetto, Margarita; Padron, Juan I.; Martin, Victor S.; Martin, Tomas Advanced Synthesis and Catalysis, 2011 , vol. 353, # 6 p. 963 - 972

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被引用次数: 11

摘要

Abstract A novel halogenation reaction from sulfonates catalyzed by iron (III) is described. The reaction can be performed as a stoichiometric or a catalytic version. This reaction provides a convenient strategy for the efficient access to structurally diverse secondary chlorides, bromides and iodides. The stereochemical course of the reaction is governed by the substrate and the experimental conditions. Secondary alcohols modified as quisylates ...