Highly Enantioselective Rh-Catalyzed Alkenylation of Imines: Synthesis of Chiral Allylic Amines via Asymmetric Addition of Potassium Alkenyltrifluoroborates to N- …
... Volume: Page: Digital Object Identifier (DOI). ... Organic Letters. ... In these examples of nonaromatic nucleophiles, however, much higher enantioinduction (90–96% ee) was achieved and no isomerization of the double bond was observed (entries 16–19). ...