Facile conversion of alcohols into esters and dihydrogen catalyzed by new ruthenium complexes

…, G Leitus, Y Ben-David, D Milstein

文献索引：Zhang, Jing; Leitus, Gregory; Ben-David, Yehoshoa; Milstein, David Journal of the American Chemical Society, 2005 , vol. 127, # 31 p. 10840 - 10841

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被引用次数: 447

摘要

An efficient, environmentally benign method for the preparation of esters from alcohols under mild, neutral conditions without the need for carboxylic acid derivatives and condensing agents was developed. Catalyst design, based on new Ru (II) hydrido carbonyl complexes incorporating electron-rich PNP and PNN ligands has resulted in the novel complex (I) which is an outstanding catalyst for the dehydrogenation of primary alcohols to ...