Organocuivreux vinyliques: II. Deuterolyse, iodolyse, couplage et alcoylation stereospecifiques des vinyl-cuivres

JF Normant, G Cahiez, C Chuit, J Villieras

文献索引：Normant,J.F. et al. Journal of Organometallic Chemistry, 1974 , vol. 77, p. 269 - 279

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被引用次数: 71

摘要

Abstract Vinylcopper derivatives, obtained by stereospecific addition of alkylcopper compounds to 1-alkynes, are transformed with retention to various ethylenic structures; 1- deutero-1-alkenes, symmetrical conjugated dienes, 1-iodo-1-alkenes, di-or tri-substituted alkenes and primary or secondary allylic alcohols.