Tetrahedron Letters

Preparation and X-ray structures of 2-[(aryl) iodonio] benzenesulfonates: novel diaryliodonium betaines

MW Justik, JD Protasiewicz, JB Updegraff

文献索引：Justik, Michael W.; Protasiewicz, John D.; Updegraff, James B. Tetrahedron Letters, 2009 , vol. 50, # 44 p. 6072 - 6075

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被引用次数: 12

摘要

Herein we present a concise preparation and characterization of 2-[(aryl) iodonio] benzenesulfonates. Determination of the X-ray crystal structure reveals a distorted trigonal bipyramidal molecular geometry about iodine and a pseudo-square geometry within the unit cell. Initial experiments point to the promising application of these compounds for unique 2- sulfonyloxyarenes.