Chemical Communications 2012-04-14

Induced circular dichroism of stereoregular vinyl polymers.

Lung-Chi Chen, Yung-Cheng Mao, Shih-Chieh Lin, Ming-Chia Li, Rong-Ming Ho, Jing-Cherng Tsai

文献索引：Chem. Commun. (Camb.) 48(30) , 3668-70, (2012)

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摘要

Stereoregular vinyl polymers, poly(2-vinyl pyridine)s (P2VPs), were synthesized to examine the tacticity effect on the induced circular dichroism (ICD) via association with chiral acids. The ICD was found to be strongly dependent on the isotacticity of the P2VPs and the acidity of chiral acid in addition to its bulkiness.This journal is © The Royal Society of Chemistry 2012