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Conformational Dynamics of Charge??Transfer States in Donor− Bridge− Acceptor Systems

…, IHM van Stokkum, HJ van Ramesdonk…

文献索引:Lauteslager, Xavier Y.; Van Stokkum, Ivo H. M.; Van John Ramesdonk; Bebelaar, Dick; Fraanje, Jan; Goubitz, Kees; Schenk, Henk; Brouwer, Albert M.; Verhoeven, Jan W. European Journal of Organic Chemistry, 2001 , # 16 p. 3105 - 3118

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被引用次数: 9

摘要

Abstract Donor− acceptor compounds containing a phenylenediamine electron donor and a naphthalene, a cyanobenzene, or a cyanonaphthalene acceptor were studied. The two chromophores are connected by three different bridging units, consisting of CH 2 groups linked to a semiflexible piperidine or piperazine ring or to a rigid 2, 5-diazabicyclo [2.2. 1] heptane group. All donor− acceptor compounds show photoinduced charge separation, ...