Unexpected and then rational synthesis of a new class of anionic phosphino–oxazoline ligands; structure and catalytic properties of a ruthenium complexElectronic …
P Braunstein, F Naud, C Graiff…
文献索引：Braunstein, Pierre; Naud, Frederic; Graiff, Claudia; Tiripicchio, Antonio Chemical Communications, 2000 , # 11 p. 897 - 898
A new class of anionic, hybrid chelating ligands is reported which contain a phosphine moiety covalently linked to an oxazoline of which the nitrogen atom formally carries a partly delocalized negative charge; the first metal complex, a ruthenium derivative, has been characterized by X-ray diffraction and shown to be active in catalytic transfer hydrogenation.
