Retro Diels–Alder reaction under mild conditions: experimental and theoretical studies

S Kotha, S Banerjee, MP Patil, RB Sunoj

文献索引：Kotha, Sambasivarao; Banerjee, Shaibal; Patil, Mahendra P.; Sunoj, Raghavan B. Organic and Biomolecular Chemistry, 2006 , vol. 4, # 10 p. 1854 - 1856

全文：HTML全文

被引用次数: 18

摘要

To circumvent the problems of decomposition or polymerization of the end products, various efforts were made to achieve the rDA reaction at lower temperature. 7 Limited reports are available regarding the factors governing the rDA reaction, and hence this poses severe restrictions in designing a simple strategy for the rDA reaction. Studies by Magnus et al. on [2.2.1]-bicyclic DA adducts have revealed that substituents such as –SiMe 3 (TMS) at the C 7 position are ...