前往化源商城

Nickel-phosphine complex-catalyzed Grignard coupling. I. Cross-coupling of alkyl, aryl, and alkenyl Grignard reagents with aryl and alkenyl halides: General scope …

K Tamao, K Sumitani, Y Kiso, M Zembayashi…

文献索引:Tamao,K. et al. Bulletin of the Chemical Society of Japan, 1976 , vol. 49, p. 1958 - 1969

全文:HTML全文

被引用次数: 596

摘要

It has been established that dihalodiphosphinenickel (II) complexes exhibit extremely high catalytic activity for selective cross-coupling of Grignard reagents with aryl and alkenyl halides. This catalytic reaction can be employed in synthetic practice for reasons of simple procedures, mild reaction conditions, high yields and high purity of the coupling products, and the wide applicability to reactions involving primary and secondary alkyl (regardless ...

 相关合成线路

~%

~%

~%

~%

~%

~%

~%

~%

~%

~%

~%

~%

~%

~%

~%

~%

~%

~%

~%

~%