The Journal of organic chemistry

Organoboron-Based Allylation Approach to the Total Synthesis of the Medium-Ring Dilactone (+)-Antimycin A1b

J Janetzko, RA Batey

文献索引：Beveridge, Ramsay E.; Batey, Robert A. Organic Letters, 2014 , vol. 16, # 9 p. 2322 - 2325

全文：HTML全文

被引用次数: 8

摘要

The stereoselective synthesis of (+)-antimycin A1b has been accomplished in 12 linear steps and 18% overall yield from (−)-ethyl lactate. A robust, scalable, and highly diastereoselective montmorillonite K10-promoted allylation reaction between an α-silyloxy