Russian journal of applied chemistry

Synthesis of Aromatic carboxylic acids by carbonylation of aryl halides in the presence of epoxide-modified cobalt carbonyls as Catalysts

VP Boyarskii, TE Zhesko, SA Lanina

文献索引：Boyarskii; Zhesko; Lanina Russian Journal of Applied Chemistry, 2005 , vol. 78, # 11 p. 1844 - 1848

全文：HTML全文

被引用次数: 14

摘要

Abstract A new procedure was developed for synthesis of aromatic and heteroaromatic acids and their derivatives (esters, salts) by carbonylation of the corresponding aryl halides. The acids are selectively formed in a high yield under very mild conditions. Highly active catalytic systems, base-containing alcoholic solutions of cobalt carbonyl modified with epoxides, were used to activate aryl halides.