… the P (CF3) 2-Ion as a Reversible CS2 Adduct,[P (CF3) 2CS2]-, and Its Potential Use as a Nucleophilic P (CF3) 2-Source: Synthesis and Structure of [18-Crown-6-K][P …

B Hoge, C Thösen, T Herrmann…

文献索引：Kolomeitsev, Alexander; Goerg, Michaela; Dieckbreder, Uwe; Lork, Enno; Roeschenthaler, Gerd-Volker Phosphorus, Sulfur and Silicon and Related Elements, 1996 , vol. 109, # 1-4 p. 597 - 600

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被引用次数: 16

摘要

... Volume: Page: ... spectra in combination with quantum theoretical calculations predicts elongated C−F and shortened P−C bonds for the P(CF 3 ... In terms of molecular orbital theory, this effect can be described as an electron donation from the phosphorus lone pair ...