Formyl (triisopropyl) silane: the synthesis and chemistry of a stable formylsilane

JA Soderquist, EI Miranda

文献索引：Soderquist, John A.; Miranda, Edgar I. Journal of the American Chemical Society, 1992 , vol. 114, # 25 p. 10078 - 10079

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被引用次数: 40

摘要

The only formylsilane isolated as a stable compound,(Me3Si), SiCH0, reported by Tilley et al. z in 1988, represented an impressive synthetic achievement, being prepared from a mixed cyclopentadienyl acylzirconium precursor. Unlike Me3SiCH0, 3* 4 (Me3Si) 3SiCH0 was found to be thermally stable although it decomposes exothermically in airs2 We wish to report the convenient preparation of formyltriisopropylsilane (2) from a modified dithiane- ...