Tetrahedron letters

Anomalous elimination of HCl from 2-chloro-1, 1-difluoroethane. Likely involvement of a 1, 2-FCl interchange mechanism

WR Dolbier, R Romelaer, JM Baker

文献索引：Dolbier Jr., William R.; Romelaer, Raphaele; Baker, J.Marshall Tetrahedron Letters, 2002 , vol. 43, # 45 p. 8075 - 8077

全文：HTML全文

被引用次数: 19

摘要

The quantitative thermal behavior of haloethanes has been a subject of consistent interest over the last half century. 1. and 2. More recently, there has been an increased interest in chlorine- and fluorine-substituted hydrochlorofluorocarbons (HCFC's) and chlorofluoroethanes in particular, because of their potential as replacements for ozone-depleting Freon refrigerants. When chlorofluoroethanes are heated in the gas phase, although free radical ...