On the reported intermediacy of vinyl radicals in spontaneous polymerization: An ESR-spin trapping study and its significance for the bond forming initiation theory
EA Mash, HG Korth, SM DeMoss
文献索引：Mash, Eugene A.; Korth, Hans-Gert; DeMoss, Suzanne M. Tetrahedron, 1997 , vol. 53, # 45 p. 15297 - 15320
Deuterated isopropyl vinyl sulfides and diethyl fumarate were synthesized and employed in a re-investigation of the mechanism of initiation of spontaneous polymerization of these comonomers by means of spin-trapping/ESR spectroscopy. Previous radical spin-trapping studies had been interpreted as indicating the involvement of vinyl radicals. While our studies produced data substantially in agreement with the previous study, it must be noted ...
