Carbohydrate Research

Degradation of 2-deoxyaldoses by alkaline hydrogen peroxide

HS Isbell, HL Frush, R Naves, P Soontracharoen

文献索引：Isbell, Horace S.; Frush, Harriet L.; Soontracharoen, Preeda Carbohydrate Research, 1980 , vol. 78, p. C7 - C10

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被引用次数: 11

摘要

Abstract Reaction of 2-deoxy-D-arabino-hexose, 2-deoxy-D-lyxo-hexose, and 2-deoxy-D- erythro-pentose with alkaline hydrogen peroxide in the presence of magnesium hydroxide afforded the corresponding 2-deoxyaldonic acid, the 1, 4-lactone, and the 1-O-formyl derivative of the next lower alditol. The 2-deoxyaldonic acids were separated in 60–80% yields, as new, crystalline lithium salts. The 1, 4-lactones were obtained under conditions ...