New Polymers Possessing a Disulfide Bond in a Unique Environment

…, AB Brummett, R Lin, M Wohlgenannt, D Quinn…

文献索引：Graf, Tyler A.; Yoo, Jun; Brummett, Adam B.; Lin, Ran; Wohlgenannt, Markus; Quinn, Daniel; Bowden, Ned B. Macromolecules, 2012 , vol. 45, # 20 p. 8193 - 8200

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被引用次数: 3

摘要

The synthesis and some of the physical properties of the first poly (disulfidediamines) are reported. The disulfidediamine functional group (R2NSSNR2) possesses a disulfide bond in a unique environment that leads to a low bond dissociation energy (calculated BDE of 43.1 kcal mol–1). These polymers were synthesized in high yields and with conversions up to> 98% by reactions between secondary diamines and a new disulfide monomer. The ...