Synthesis of N??Alkoxy Amines via Catalytic Oxidation of Hydrocarbons

…, F Schwarzenbach, PA van der Schaaf…

文献索引：Kirner, Hans-J.; Schwarzenbach, Franz; Van Der Schaaf, Paul A.; Hafner, Andreas; Rast, Valerie; Frey, Markus; Nesvadba, Peter; Rist, Guenther Advanced Synthesis and Catalysis, 2004 , vol. 346, # 5 p. 554 - 560

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被引用次数: 12

摘要

Abstract: Sterically hindered N-alkoxy amines 3 are synthesized in good yields by coupling nitroxides 2 with hydrocarbyl radicals generated in situ by t- BuOOH hydrogen abstraction from hydrocarbons. The reaction is catalyzed by copper halides as well as by onium iodides. ... Keywords: N-alkoxy amines; tert-butyl hydroperox- ide; copper; hydrocarbons; nitroxides; oxidation; phase-transfer catalysis; radical reactions; TEMPO