Chemical Communications 2013-10-14

Scalable synthesis of quaterrylene: solution-phase 1H NMR spectroscopy of its oxidative dication.

Rajesh Thamatam, Sarah L Skraba, Richard P Johnson

文献索引：Chem. Commun. (Camb.) 49(80) , 9122-4, (2013)

摘要

Quaterrylene is prepared in a single reaction and high yield by Scholl-type coupling of perylene, utilizing trifluoromethanesulfonic acid as catalyst and DDQ or molecular oxygen as oxidant. Dissolution in 1 M triflic acid/dichloroethane with sonication yields the aromatic quaterrylene oxidative dication, which is characterized by its (1)H NMR spectrum.

结构式	名称/CAS号	分子式	全部文献
	benzo(1,2,3-cd:4,5,6-c'd')diperylene CAS:188-73-8	C₄₀H₂₀

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Scalable synthesis of quaterrylene: solution-phase 1H NMR spectroscopy of its oxidative dication.

摘要

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