Highly selective heterogeneous palladium-catalyzed hydrogenations using triethoxysilane and water

JM Tour, JP Cooper, SL Pendalwar

文献索引：Tour, James M.; Cooper, Joel P.; Pendalwar, Shekhar L. Journal of Organic Chemistry, 1990 , vol. 55, # 11 p. 3452 - 3453

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被引用次数: 58

摘要

Summary: Treatment of alkenes or alkynes at ambient temperature with triethoxysilane and 5 mol% of palladium (I1) acetate in a mixture of tetrahydrofuran and water affords the corresponding hydrogenated products. Excellent chemosclectivities and stereoselectivities can be obtained using this process.

~96%

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~89%

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~99%

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~82%

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~98%

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~10%

7737-62-4

3-氧代庚酸乙酯

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