The Synthesis of 3-Chloro-2-chloromethyl-1-propene from Pentaerythritol1

A Mooradian, JB Cloke

文献索引：Mooradian; Cloke Journal of the American Chemical Society, 1945 , vol. 67, p. 943

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被引用次数: 50

摘要

The present work on 3-chloro-2-chloromethyl-1-propene (I), H~ C= C (CHL! l) z, was undertaken in connection with a study of certain chlorinated ethylenic hydrocarbons and nitriles to be reported in a later paper. KleinfellerZ first announced the preparation of a mixture of (I) and 1, 3-dichloro-2-chloromethyl-1-propene (11) in 70% yield by the action of sodium amalgam on 5 g. lots of 1~ 3-dichloro-2-nitro-2-chloromethyl-propane, OtN-C ( ...