Dalton Transactions

Synthesis of (arylimido) vanadium complexes and their application for oxidative coupling reactions of silyl enol ether derivatives

M Nishina, T Moriuchi, T Hirao

文献索引：Nishina, Masafumi; Moriuchi, Toshiyuki; Hirao, Toshikazu Dalton Transactions, 2010 , vol. 39, # 41 p. 9936 - 9940

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被引用次数: 11

摘要

(Arylimido) vanadium (V) complexes, V (NAr)(OEt) Cl2 [Ar= C6H5, p-BrC6H4, p-(MeO) C6H4] or V (NAr) Cl3 [Ar= o-BrC6H4, o-(MeO) C6H4] were synthesized by the reaction of VO (OEt) Cl2 or VOCl3, respectively, with the corresponding aryl isocyanates. X-Ray crystal structure determination for V (NAr)(OEt) Cl2 (Ar= C6H5 and p-BrC6H4) elucidates the alkoxido-bridged dimeric building blocks [V (NAr)(OEt) Cl2] 2, wherein the substituent on ...