Rates and alkyl group size in solvolysis of alkyl derivatives

M Orlovic, O Kronja, K Humski, S Borcic…

文献索引：Orlovic, Mirko; Kronja, Olga; Humski, Kresimir; Borcic, Stanko; Polla, Eugenio Journal of Organic Chemistry, 1986 , vol. 51, # 17 p. 3253 - 3256

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被引用次数: 15

摘要

Results The series of tertiary chlorides 1 and secondary chlorides 2 were prepared by the reaction of the parent alcohols with thionyl chloride. The series of secondary tosylates 3 was prepared from the corresponding alcohols and p-toluenesulfonyl chloride in pyridine. All parent alcohols were prepared from the corresponding Grignard reagents (RMgBr) and acetone (I), benzaldehyde (2), and acetaldehyde (3), respectively. Alkyl group R ...