Transformation regioselective de cetones en cetols α primaires ou secondaires

T Cuvigny, G Valette, M Larcheveque…

文献索引：Cuvigny,T. et al. Journal of Organometallic Chemistry, 1978 , vol. 155, p. 147 - 155

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被引用次数: 20

摘要

Abstract The oxidation of α ketone imine carbanions gives primary α ketols from methylketones, and secondary α ketols from symmetric ketones. Secondary α ketols may also be isolated by oxidation of carbanions of methylketone oximes. By using manganese dioxide, these secondary ketols may be oxidized to α diketones.