Selectivity control in substituted fatty amines synthesis from esters or nitriles in the presence of bifunctional catalysts

…, N Suppo-Essayem, A Piccirilli, C Guimon

文献索引：Barrault; Brunet; Suppo-Essayem; Piccirilli; Guimon JAOCS, Journal of the American Oil Chemists' Society, 1994 , vol. 71, # 11 p. 1231 - 1238

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被引用次数: 1

摘要

Abstract Copper chromite-type catalysts, supported by alumina or graphite and promoted with barium, were used for the onestep synthesis of tertiary fatty amines [R 2 NCH 3 or RN (CH 3) 2] from ester, acid or nitrile and ammonia, methanol and hydrogen. The surface composition of the catalysts, studied by X-ray photoelectron spectroscopy and by adsorption experiments, showed that there was a correlation between selectivity and the presence of ...