Tetrahedron

Hydrogénolyse en phase liquide sur Pd/C des époxydes du carvomenthène et du limonène

G Accrombessi, P Geneste, JL Olivé, AA Pavia

文献索引：Accrombessi, G.; Geneste, P.; Olive, J.-L.; Pavia, A. A. Tetrahedron, 1981 , vol. 37, # 18 p. 3135 - 3140

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被引用次数: 12

摘要

Hydrogenolysis over Pd/C of cis and trans epoxides of carvomenthene and limonene give a mixture of hydrocarbons, secondary and tertiary alcohols, and ketones in proportions dependent upon the nature of the starting material. In the limonene epoxides, the extracyclic double bond plays an important role in the opening of the oxirane ring through a common unsaturated tertiary alcohol intermediate by double bond migration, hydrogenation of ...