前往化源商城

The Effect of Ring Size on the Rate of Solvolysis of the 1-Chloro-1-methylcycloalkanes1, 2

HC Brown, M Borkowski

文献索引:Brown; Borkowski Journal of the American Chemical Society, 1952 , vol. 74, p. 1894,1900

全文:HTML全文

被引用次数: 125

摘要

Cyclic compounds undergoing reaction at a ring atom exhibit striking changes in reactivity with variation in ring size. These dHerences in chemical behavior have been attributed to the changes in internal strain in the cyclic structures which accompany changes in the coordination number of the ring atom undergoing reaction (I-strain). To test the validityof the interpretation, the 1-chloro-1-methylcycloalkanes with rings of 4-, 5-, 6-, 7-, 8-, 9-, IO-, 11-, ...