Tetrahedron letters

C–N bond formation followed by N–Cl bond breaking. One more and unexpected case of the formation of a hydroxamic group via heterolytic bond cleavage

IV Vrček, V Pilepić, S Uršić

文献索引：Vinkovic Vrcek, Ivana; Pilepic, Viktor; Ursic, Stanko Tetrahedron Letters, 2004 , vol. 45, # 4 p. 699 - 702

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被引用次数: 6

摘要

An unexpected and previously unknown reaction sequence in the interactions of the acyl halides with nitrosobenzenes, which involves carbon–nitrogen bond formation followed by heterolytic nitrogen–chlorine bond cleavage giving the corresponding unsubstituted N- phenylalkylhydroxamic acids (or N-phenylarylhydroxamic acids) and chlorine as the products has been observed. The kinetic and other evidence obtained suggest that the ...