Journal of Organic Chemistry

Metal-ammonia reduction. VII. Stereospecific reduction in the phenanthrene series

PW Rabideau, RG Harvey

文献索引：Rabideau,P.W.; Harvey,R.G. Journal of Organic Chemistry, 1970 , vol. 35, p. 25 - 30

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被引用次数: 45

摘要

Results Phenanthrene, in accord with theoretical prediction, 4 underwent preferential lithium- ammonia reduction at the 9, lO position. 3a However, under conditions previously demonstrated to provide efficient transformation of acene hydrocarbons to dihydro derivatives, a reduction of phenanthrene and 9-methylphenanthrene was incomplete and accompanied by secondary products (Table I, experiments 1, 2, and 9). A brief ...