Methylsulfinyl Carbanion (CH3-SO-CH2-). Formation and Applications to Organic Synthesis

EJ Corey, M Chaykovsky

文献索引：Corey,E.J.; Chaykovsky,M. Journal of the American Chemical Society, 1965 , vol. 87, p. 1345 - 1353

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被引用次数: 498

摘要

A detailed account is given of the generation of the conjugate base of dimethyl sulfoxide (methq~ lsulJinql1 carbanion). The chemical properties and utility of this reagent are illustrated by a number of synthetic applications. For example, a new si-nthetic route to ketones is described.