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Halogenation and nitration of naphtho [1, 2??c][1, 2, 5] thiadiazole

…, JM Patterson, AC Kovelesky

文献索引:Smith, Walter T.; Patterson, John M.; Kovelesky, Albert C. Journal of Heterocyclic Chemistry, 1991 , vol. 28, # 3 p. 813 - 816

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被引用次数: 1

摘要

Abstract Bromination of naphtho [1, 2-c][1, 2, 5] thiadiazole (I) gives either an addition product, 4, 5-dibromo-4, 5-dihydronaphtho [1, 2-c][1, 2, 5] thiadiazole (II), or a substitution product, 5, 6-dibromonaphtho [1, 2-c][1, 2, 5] thiadiazole (III), depending on the reaction conditions. Dehydrobromination of II gives 5-bromonaphtho [12-c][1, 2, 5] thiadiazole (IV). Chlorination of I gives the corresponding addition product V or 5-chloronaphtho [1, 2-c][1, ...