Intermolecular Ritter-type C–H amination of unactivated sp3 carbons

Q Michaudel, D Thevenet, PS Baran

文献索引：Michaudel, Quentin; Thevenet, Damien; Baran, Phil S. Journal of the American Chemical Society, 2012 , vol. 134, # 5 p. 2547 - 2550

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被引用次数: 93

摘要

Intermolecular Ritter-type C–H amination of unactivated sp3 carbons has been developed. This new reaction proceeds under mild conditions using readily available reagents and an inexpensive source of nitrogen (acetonitrile). A broad scope of substrates can be aminated with this method since many functional groups are tolerated. This reaction also allows for the direct, innate C–H amination of a variety of hydrocarbons such as cyclohexane without the ...