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A one-pot selective deprotective acetylation of benzyl ethers and OTBDMS ethers using the BF 3· Et 2 O–NaI–Ac 2 O reagent system

A Brar, YD Vankar

文献索引:Brar, Anita; Vankar, Yashwant D. Tetrahedron Letters, 2006 , vol. 47, # 29 p. 5207 - 5210

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被引用次数: 21

摘要

An efficient selective deprotection followed by acetylation of several benzyl ethers, including 6-OBn ethers of monosaccharides, and-OTBDMS ethers has been developed by using the BF3· Et2O–NaI–Ac2O reagent system. In addition, both benzylidene and isopropylidene groups are deprotected to form the corresponding diacetates.