Journal of the American Chemical Society

Oxidative Reactions of Hydrazines. IV. Elimination of Nitrogen from 1, 1-Disubstituted-2-arenesulfonhydrazides1-4

LA Carpino

文献索引：Carpino Journal of the American Chemical Society, 1957 , vol. 79, p. 4427,4429

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被引用次数: 153

摘要

Alkaline degradation of 1, 1-dibenzyl-2-benzenesulfonhydrazides leads to the formation of bibenzyls. The reaction is represented as proceeding through an intermediate formed by a- elimination of the elements of benzenesulfinic acid. A new method of introducing the very conveniently removed carbo-t-butoxy group is described involving acylation by t-butyl azidoformate.