Guang pu xue yu guang pu fen xi = Guang pu 2004-12-01

[A study on europium sensitized chemiluminescence of pipemidic acid].

Xia Li, Hong Qiang, Xiao-li Wang, Shi-lü Chen, Hui-chun Zhao

文献索引：Guang Pu Xue Yu Guang Pu Fen Xi 24(12) , 1518-20, (2004)

全文：HTML全文

摘要

A flow injection chemiluminescence method for the determination of Pipemidic acid (PPA) was developed. It is based on luminescence produced with KMnO4-Na2S2O4 CL system sensitized by Eu3+-PPA. The familar excipients such as starch and dextrine do not cause interference. The several kinds of affect on chemiluminescence were studied. The linear range and detection limit for PPA are 7.00 x 10(-9)-9.00 x 10(-7) mol x L(-1) and 4.09 x 10(-9) mol x L(-1), respectively. This method have successfully been applied to the determination of PPA in tablet and urine. And the mechanism of chemiluminescence is proposed.