Journal of the American Chemical Society

Mechanistic Studies of the Reaction of Dioxygen with Dinuclear Iron (II) Compounds to Form (. mu.-Peroxo) diiron (III) Complexes

AL Feig, SJ Lippard

文献索引：Feig, Andrew L.; Lippard, Stephen J. Journal of the American Chemical Society, 1994 , vol. 116, # 18 p. 8410 - 8411

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被引用次数: 30

摘要

Carboxylate-bridged non-heme diiron (I1) centers occur in several metalloenzymes involved in the biological utilization of di~ xygen. l-~ X-ray structural information is now available for three proteins in this class, hemerythrin (Hr), 6 the R2 protein of Escherichia coli ribonucleotide reductase (RR),'and the hydroxylase protein of soluble methane monooxygenase (MM0). 8 In each of the three biological systems, 0 2 binds to the ...