Radical Intermediates in the Thermal Decomposition of 1, 1-Bis (t-butyldioxy) cyclohexane.

…, H Kumura, T Nakamura, S Suyama, Y Sawaki

文献索引：Sugihara, Yasushi; Watanabe, Yasumasa; Kumura, Hiromi; Nakamura, Tomoyuki; Suyama, Shuji; Sawaki, Yasuhiko Bulletin of the Chemical Society of Japan, 1992 , vol. 65, # 3 p. 664 - 667

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被引用次数: 10

摘要

The thermolysis mechanism of 1, 1-bis (t-butyldioxy) cyclohexane (6) has been studied in solutions. The activation parameters obtained in cumene are ΔH≠= 139.5 kJ mol− 1 and ΔS≠= 44.8 JK− 1 mol− 1, and the volatile products are t-butyl alcohol, t-butyl peroxyhexanoate, and 2, 3-dimethyl-2, 3-diphenylbutane along with minor products of acetone, cyclohexanone, and t-butyl 1-methyl-1-phenylethyl peroxide. The thermolysis of ...