Mechanism of SNi reactions. The effect of the base strength of the anionic fragments

DJ Verrinder, MJ Hourigan…

文献索引：Verrinder,D.J. et al. Canadian Journal of Chemistry, 1978 , vol. 56, p. 2582 - 2589

全文：HTML全文

被引用次数: 3

摘要

The kinetics and stereochemical aspects of the thermal decomposition of aralkyl carbonates, thiocarbonates, and carbamates were examined. The rates for the decompositions as well as the rates of loss of optical activity followed first-order kinetics. The decompositions appear to involve the heterolysis of the aralkyl-oxygen bond followed by the breakdown of the subsequent ion pair via a cyclic mechanism. However, it was found that this ion pair could ...