The Journal of Organic Chemistry

Evidence for hyperconjugative stabilization of olefins from tautomeric equilibria

LJ Dolby, GN Riddle

文献索引：Dolby,L.J.; Riddle,G.N. Journal of Organic Chemistry, 1967 , vol. 32, p. 3481 - 3485

全文：HTML全文

被引用次数: 11

摘要

The importance of hyperconjugation has been controversial for a good many years. In particular, there is a lack of experimental observations which indicate that hyperconjugation is significant in the ground states of neutral molecule^.^*^ Over the years, many tautomeric equilibria have been examined in an effort to determine the extent of hyperconjugative stabilization at a given center. However, most of the systems studied were complicated by ...