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The Synthesis of Arylphosphonic and Diarylphosphinic Acids by the Diazo Reaction1

GO Doak, LD Freedman

文献索引:Doak; Freedman Journal of the American Chemical Society, 1951 , vol. 73, p. 5658

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被引用次数: 46

摘要

A study of the reaction between the halides of certain elements and dry diazonium salts in organic solvents has been initiated in this Laboratory. The first paper of this series describes the results obtained using arsenic trichloride and diazonium fluoborates. 2 The present paper reports an extension of this reaction to phosphorus trichloride. Several methods have been previously used for the preparation of arylphosphonic acids. None of these reactions ...