Journal of fluorine chemistry

Metal bis (perfluorooctanesulfonyl) amides as highly efficient Lewis acid catalysts for fluorous biphase organic reactions

X Hao, A Yoshida, J Nishikido

文献索引：Hao, Xiuhua; Yoshida, Akihiro; Nishikido, Joji Journal of Fluorine Chemistry, 2006 , vol. 127, # 2 p. 193 - 199

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被引用次数: 34

摘要

In fluorous biphase system, metal bis (perfluorooctanesulfonyl) amides are better Lewis acid catalysts than the analogous triflates toward either transesterifications, or direct esterifications, or Friedel–Crafts acylations or Baeyer–Villiger oxidations. These catalysts are selectively soluble in lower fluorous phase and can be recovered simply by phase separation. Furthermore, these catalysts can be reused without decrease of activity in ...